Competitive adsorption and mobility sequence of heavy metals in urban soils of southeastern China

作     者：ZHANG Ming-kui FANG Li-ping HUANG Chang-yong 

作者机构：Department of Natural Resource Sciences College of Natural Resource and Environmental Sciences Zhejiang University Hangzhou 310029 China 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2006年第18卷第2期

页      面：329-333页

核心收录：

学科分类：12[管理学] 1204[管理学-公共管理] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 082803[工学-农业生物环境与能源工程] 08[工学] 0828[工学-农业工程] 120405[管理学-土地资源管理] 

基　　金：TheNationalK eyBasicResearchProgram ofChina (No.2005CB121104 2002CB410804)andtheNationalN aturalScienceFoundationofChina(N o.40471064) 

主　　题：competitive adsorption mobility sequence heavy metal urban soil 

摘      要：Heavy metals can be introduced into urban soils at the same time. Therefore, their selective retention and competitive adsorption by the soils become of major importance in determining their availability and movement throughout the soil. In this study, the availability and mobility of six heavy metals in eight urban soils collected from different cities of Zhejiang Province, southeastern China were assessed using distribution coefficients（Kd） and retardation factor（Rf）. The results showed that there were great differences in the Kd and Rfamong the tested soils. The adsorption sequences were Cr〉Pb〉Cu〉Cd〉Zn〉Ni, and the Kd decreased with increasing levels of metal addition. Ni generally has the lowest Rf values followed closely by Cd, and Zn whereas Cr and Pb reached the highest values. The results suggest that Ni and Zn have the highest mobility associated to the lowest adsorption, Cr and Pb present the opposite behavior. Correlation analysis indicates that soil pH, CaCO3 content, and cation exchange capacity （CEC） are key factors controlling the solubility and mobility of the metals in the urban soils.