经由可逆碳碳键断裂的去消旋化反应
Deracemization through C-C bond manipulation作者机构:Beijing National Laboratory for Molecular Sciences(BNLMS)Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Department of ChemistryUniversity of ChicagoChicago IL 60637USA
出 版 物:《Science Bulletin》 (科学通报(英文版))
年 卷 期:2024年第69卷第3期
页 面:285-287页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:Asymmetric catalysis has proven remarkably successful in achieving enantioselective control during the construction of new stereogenic ***,the challenge of achieving chiral enrichment at pre-existing stereogenic centers,without introducing additional molecular variations,remains a rare and intriguing pursuit known as asymmetric stereochemical editing[1–3].