Geochemistry, mineral paragenesis and geothermal conditions of oreforming fluids from the Ain El Bey Cu–Fe deposit: potential occurrence of native gold and precious metal traces (North African orogenic belt, Northern Tunisia)

作     者：Rania Ben Aissa Wiem Ben Aissa Said Tlig Lassaad Ben Aissa Abdessalem Ben Haj Amara Rania Ben Aissa;Wiem Ben Aissa;Said Tlig;Lassaâd Ben Aissa;Abdessalem Ben Haj Amara

作者机构：Faculty of Science of BizerteUniversity of Carthage7021 ZarzounaBizerteTunisia Laboratoire de Recherche RessourcesMateriaux et EcosystemesUniversity of Carthage7021 ZarzounaBizerteTunisia Department of GeologyUniversity Claude Bernard Lyon 169622 VilleurbanneFrance Faculty of Science of TunisUniversity of Tunis-El ManarRommana1068 TunisTunisia 

出 版 物：《Acta Geochimica》 (地球化学学报（英文）)

年 卷 期：2024年第43卷第2期

页      面：366-384页

核心收录：

学科分类：081803[工学-地质工程] 08[工学] 0708[理学-地球物理学] 0818[工学-地质资源与地质工程] 

基　　金：funded by the “Laboratoire de Recherche Ressources  Matériaux et Ecosystémes”  University of Carthage 7021 Zarzouna  Bizerte  Tunisia 

主　　题：Ore-formingfluids Mineral geochemistry Mineral geothermometers Native silver-gold Ain El Bey Ore deposit North Tunisia 

摘      要：The Ain El Bey abandoned mine, in North-West Tunisia, fits into the geodynamic context of the European and African plate boundary. Ore deposit corresponds to veins and breccia of multiphase Cu–Fe-rich mineralization related to various hydrothermal fluid circulations. Petromineralogical studies indicate a rich mineral paragenesis with a minimum of seven mineralization phases and, at least, six pyrite generations. As is also the case for galena and native silver, native gold is observed for the first time as inclusion in quartz which opens up, thus, new perspectives for prospecting and evaluating the potential for noble metals associated with the mineralization. Scanning Electron Microscope--Energy Dispersive Spectroscopy and Transmission electron microscopy analyses show, in addition, a large incorporation of trace elements, including Ag and Au, in mineral structures such as fahlores(tetrahedrite-tennantite) and chalcopyrite ones. The mineral/mineral associations, used as geothermometers, gave estimated temperatures for the mineralizing fluids varying from 254 to 330 ℃ for phase Ⅲ, from 254 to 350 ℃ for phase Ⅳ, and from 200 to 300 ℃ for phases Ⅴ and Ⅵ. The seventh and last identified mineralization phase, marked by a deposit of native gold, reflects a drop in the mineralizing fluid’s temperature( 200 ℃) compatible with boiling conditions. Such results open up perspectives for the development of precious metal research and the revaluation of the Cu–Fe ore deposit at the Ain El Bey abandoned mine, as well as at the surrounding areas fitting in the geodynamic framework of the Africa-Europe plate boundary.