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Michael Addition Reaction without Catalyst: The Synthesis of 2-Amino-5, 6, 7, 8-tetrahydro-5-oxo-4-aryl-7, 7-dimethyl- 4H-benzo-[b]-pyran Derivatives

Michael Addition Reaction without Catalyst: The Synthesis of 2-Amino-5, 6, 7, 8-tetrahydro-5-oxo-4-aryl-7, 7-dimethyl- 4H-benzo-[b]-pyran Derivatives

作     者:Shu Jiang TU Xiao Hong LIU Heng Jun MA Da Qing SHI Fang LIU 

作者机构:Department of ChemistryXuzhou Normal UniversityXuzhou 221009 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2002年第13卷第5期

页      面:393-395页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主  题:Benzo-[b]-pyran dimetone ethylene glycol. 

摘      要:A series of tetrahydrobenzo-[b]-pyran derivative was synthesized by the reaction of arylmethylene malononitrile or arylmethylene cyanoacetate with dimedone in ethylene glycol at 80C without catalyst. The structures of the two products were characterized by X-ray diffraction.

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