Spin switching in corrole radical complex

作     者：Chunyan Yu Hongping Xiao Hua Lu Yongshu Xie Chunyan Yu;Hongping Xiao;Hua Lu;Yongshu Xie

作者机构：College of MaterialChemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material Technology of Ministry of EducationHangzhou Normal UniversityHangzhou 311121China College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Functional Materials ChemistryKey Laboratory for Advanced Materials and Institute of Fine ChemicalsSchool of Chemistry&Molecular EngineeringEast China University of Science&TechnologyShanghai 200237China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第1期

页      面：1-2页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Corrole inner radical 

摘      要：Spintronics is a cutting-edge field of developing new electronic devices by manipulating the electron spin and magnetic moment[1].Traditional spintronic research mainly focuses on transition metals and inorganic semiconductors,while organic molecules have the advantage of being extremely easy to realize efficient spin control by modifying the specific external conditions for desired electronic structures and magnetic ***,as a ring-contracted porphyrin,is the aromatic analog of the central macrocycle of vitamin *** has a squeezed inner cavity and three inner NHs in its free-base form,making it easier to stabilize high-valent metal ions and thus a promising candidate in spintronics.