Partial oxidation of methane by photocatalysis

作     者：Zhongshan Yang Qiqi Zhang Hui Song Xin Chen Jiwei Cui Yanhui Sun Lequan Liu Jinhua Ye Zhongshan Yang;Qiqi Zhang;Hui Song;Xin Chen;Jiwei Cui;Yanhui Sun;Lequan Liu;Jinhua Ye

作者机构：TJU-NIMS International Collaboration LaboratorySchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China International Center for Materials Nanoarchitectonics(WPI-MANA)National Institute for Materials Science(NIMS)1-1 NamikiIbaraki 3050047Japan Zhejiang LAMP Co.Ltd.Wenzhou 325206China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2024年第35卷第1期

页      面：153-168页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Key R&D Program of China(No.2021YFA1500800) National Natural Science Foundation of China(No.22072106) 

主　　题：Partial oxidation of methane Photocatalysis Liquid oxygenates Oxidants C-H activation 

摘      要：Methane chemistry is one of the“Holy Grails of catalysis.It is highly desirable but challenge to transform methane into value-added chemicals,because of its high C-H bonding energy(435 kJ/mol),lack ofπbonding or unpaired ***,commercial methane conversion is usually carried out in harsh conditions with enormous energy *** partial oxidation of methane to liquid oxygenates(PPOMO)is a future-oriented technology towards realizing high efficiency and high selectivity under mild *** selection of oxidant is crucial to the PPOMO ***,attentions are paid to the research progress of PPOMO with various oxidants(O_(2),H_(2)O,H_(2)O_(2)and other oxidants).Moreover,the activation of the selected oxidants is also highly ***,we summarized the methane activation mechanisms focusing on the C-H bond that was broken mainly by·OH radical,O-specie or photogenerated hole(h+).Finally,the challenges and prospects in this subject are briefly discussed.