Mechanical Strong,Highly Adhesive,Recyclable and Transparent Supramolecular Silicone Coatings with Easy Water/Oil Sliding

作     者：Yu-Cai Lin Feng Chen Shou-Bin Yang Shu-Yue Gong Yu-Xiang Luo Fang-Fang Wei Fu-Chuan Ding Wei-Bin Bai Rong-Kun Jian Yu-Cai Lin;Feng Chen;Shou-Bin Yang;Shu-Yue Gong;Yu-Xiang Luo;Fang-Fang Wei;Fu-Chuan Ding;Wei-Bin Bai;Rong-Kun Jian

作者机构：Fujian Key Laboratory of Polymer MaterialsFujian Provincial Key Laboratory of Advanced Materials Oriented Chemical EngineeringCollege of Chemistry and Materials ScienceFujian Normal UniversityFuzhou 350007China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学(英文版))

年 卷 期：2023年第41卷第11期

页      面：1796-1804,I0010页

核心收录：

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(Nos.22005053 and 21978050) the Fujian Provincial Department of Science and Technology(No.2021J05032) Department of Education(Fujian province)(No.JAT190076)。 

主　　题：Silicong coating Supramolecular Adhesion Recyclable 

摘      要：Traditional silicone materials have poor mechanical properties,poor interfacial adhesion and lack the ability to be reprocessed or recycled.Herein,we developed a novel strategy of incorporating dynamic noncovalent bonds(2-amino-4-hydroxy-6-methylpyrimidine(UPy))into side chain of silicone backbones to construct supramolecular silicone poly(urea-urethane)(SSPu)coatings with excellent mechanical performance,strong interfacial adhesion and multiple time recycling capability.Impressively,the prepared SSPu is endowed with simultaneously enhanced stiffness(272.0±23.2 MPa)and toughness(8.0±2.0 MJ·m^(-3)).Besides,SSPu shows strong interfacial adhesion(up to 9.0±1.3 MPa)to diverse substrate(stainless steel,aluminum,copper,epoxy and glass)with long term stability.Moreover,SSPu exhibits excellent multirecyclability and reusability without significantly decrease of its performance.In addition to the abovementioned features,the enrichment of siloxane backbones in the surface layer endows SSPu with robust repellency to water/oil.Our strategy provides a powerful route to fabricate a new multifunctional silicone elastomer.It is highly anticipated that our strategy can effectively extend the service life of silicone coating which can be applied in a wide variety of areas including self-cleaning,antifouling.