Electrochemical hydrogen evolution efficiently boosted by interfacial charge redistribution in Ru/MoSe_(2) embedded mesoporous hollow carbon spheres

作     者：Yubin Kuang Wei Qiao Fulin Yang Ligang Feng Yubin Kuang;Wei Qiao;Fulin Yang;Ligang Feng

作者机构：School of Chemistry and Chemical EngineeringYangzhou UniversityYangzhou 225002JiangsuChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学(英文版))

年 卷 期：2023年第85卷第10期

页      面：447-454,I0012页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0806[工学-冶金工程] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (21972124, 22272148) the Priority Academic Program Development of Jiangsu Higher Education Institution。 

主　　题：Hydrogen evolution reaction Ruthenium Electrocatalyst MoSe_(2) Mesoporous hollow carbon spheres 

摘      要：The strong metal-support interaction inducing combined effect plays a crucial role in the catalysis reaction. Herein, we revealed that the combined advantages of MoSe_(2), Ru, and hollow carbon spheres in the form of Ru nanoparticles(NPs) anchored on a two-dimensionally ordered MoSe_(2) nanosheet-embedded mesoporous hollow carbon spheres surface(Ru/MoSe_(2)@MHCS) for the largely boosted hydrogen evolution reaction(HER) performance. The combined advantages from the conductive support, oxyphilic MoSe_(2), and Ru active sites imparted a strong synergistic effect and charge redistribution in the Ru periphery which induced high catalytic activity, stability, and kinetics for HER. Specifically, the obtained Ru/MoSe_(2)@MHCS required a small overpotential of 25.5 and 38.4 mV to drive the kinetic current density of 10 mA cm^(-2)both in acid and alkaline media, respectively, which was comparable to that of the Pt/C catalyst. Experimental and theoretical results demonstrated that the charge transfer from MoSe_(2) to Ru NPs enriched the electronic density of Ru sites and thus facilitated hydrogen adsorption and water dissociation. The current work showed the significant interfacial engineering in Ru-based catalysts development and catalysis promotion effect understanding via the metal-support interaction.