Neighboring effect in single-atom catalysts for the electrochemical carbon dioxide reduction reaction

作     者：Hon Ho Wong Mingzi Sun Tong Wu Cheuk Hei Chan Lu Lu Qiuyang Lu Baian Chen Bolong Huang 

作者机构：Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARChina Research Centre for Carbon-Strategic CatalysisThe Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARChina 

出 版 物：《eScience》 (电化学与能源科学（英文）)

年 卷 期：2024年第4卷第1期

页      面：1-16页

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the support from the National Natural Science Foundation of China Grant Council of Hong Kong Joint Research Scheme(N_PolyU502/21) the funding for Projects of Strategic Importance of The Hong Kong Polytechnic University(Project Code:1-ZE2V) Shenzhen Fundamental Research Scheme-General Program(JCYJ20220531090807017) the Natural Science Foundation of Guangdong Province(2023A1515012219) Departmental General Research Fund(Project Code:ZVUL)from Department of Applied Biology and Chemical Technology of Hong Kong Polytechnic University 

主　　题：Carbon dioxide reduction Neighboring effect Atomic catalysts Electronic modulations Active sites 

摘      要：Although single-atom catalysts(SACs)have attracted enormous attention for their applications in the electrochemical reduction of CO_(2)(CO_(2)RR)due to their extraordinary catalytic activity and well-defined active centers,neighboring effects and their influence on the electrochemical performance of SACs have not been well *** this review,we present a summary of the neighboring effects on SACs for the CO_(2)RR process,where the surrounding atoms not only induce electronic modulation of the metal atom but also participate in the CO_(2)*** theoretical and experimental studies have pointed out that the neighboring sites of the anchored metal center can provide second active/adsorption locations during the catalytic process,enhancing CO_(2)RR performance *** review supplies advanced insights into the significant roles and impacts of neighboring effects on the catalytic process,which also benefit the development of advanced SACs to achieve efficient electrocatalysis.