Recent advances in catalytica symmetric Buchner reaction

作     者：Chong-Yang Shi Guang-Yu Zhu Yin Xu Ming-Yu Teng Long-Wu Ye Chong-Yang Shi;Guang-Yu Zhu;Yin Xu;Ming-Yu Teng;Long-Wu Ye

作者机构：College of Chemistry and Chemical EngineeringYunnan Normal UniversityKunming 650500China Key Laboratory of Chemical Biology of Fujian ProvinceState Key Laboratory of Physical Chemistry of Solid Surfacesand College of Chemistry and Chemical EngineeringXiamenUniversity.Xiamen361005China State Key Laboratory of Organometallic ChemistryShanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2023年第34卷第12期

页      面：87-92页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：support from MoST(No.2021YFC2100100) the National Natural Science Foundation of China(No.22125108) Yunnan Normal University,and Applied Basic Research Projects of Yunnan Province(No.202101AT070217) 

主　　题：Bichner reaction Diazo compounds Metal carbenes Cycloheptatrienes Dearomatization reactions 

摘      要：Bichner reaction,as a unique type of expansive dearomatization,has become a practical strategy for the straightforward assembly of valuable functionalized cycloheptatrienes from ubiquitous aromatic *** the asymmetric version has been investigated since the early 1990s,enantioselective Bichner reaction is still limited by the catalyst type and substrate *** review aims to propose the limitation and possible development direction of this field by summarizing the evolution of catalytic asymmetric Bichner reaction,which is organized on the basis of intra-and intermolecular *** the different metal carbene precursors,the reactions are further classified by carbene sources.