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SOLID-LIQUID PHASE TRANSFER CATALYTIC SYN THESIS Ⅸ: THE SYNTHESIS OF α-AMINO ACIDS VIA ALICYLATION OF ALDIMINE UNDER MICROWAVE IRRADIATION,

SOLID-LIQUID PHASE TRANSFER CATALYTIC SYN THESIS Ⅸ: THE SYNTHESIS OF α-AMINO ACIDS VIA ALICYLATION OF ALDIMINE UNDER MICROWAVE IRRADIATION,

作     者:Run Hua DENG Ai Qiao MI Yao Zhong JIANG Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1993年第4卷第5期

页      面:381-384页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

主  题:SYN THE SYNTHESIS OF AMINO ACIDS VIA ALICYLATION OF ALDIMINE UNDER MICROWAVE IRRADIATION SOLID-LIQUID PHASE TRANSFER CATALYTIC SYN THESIS VIA 

摘      要:The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of alkylated products the corresponding α-amino acids were obtained in overall yield 43.6~62.5%.

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