Chiral porphyrin assemblies
作者机构：Beijing National Laboratory for Molecular Science(BNLMS)CAS Key Laboratory of ColloidInterface and Chemical ThermodynamicsInstitute of ChemistryChinese Academy of SciencesBeijingP.R.China Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline MaterialsDepartment of ChemistryUniversity of Science and Technology BeijingBeijingP.R.China
出 版 物：《聚集体(英文)》 (Aggregate)
年 卷 期：2023年第4卷第1期
页 面：27-40页
核心收录：
学科分类：0710[理学-生物学] 07[理学] 070303[理学-有机化学] 0703[理学-化学] 0836[工学-生物工程]
基 金：National Natural Science Foundation of China,Grant/Award Numbers:92156018,21972150,21890734 CAS Project for Young Scientists in Basic Research,Grant/Award Number:YSBR-027。
主 题：chiral circularly polarized luminescence helical porphyrins self-assembly
摘 要：Porphyrins are among the most important macrocycles because they perform many essential functions in living systems and serve as building blocks in many functional materials.Incorporating the chirality into porphyrins can aid biomimetic research and the exploration of new functional materials.In this review,recent developments in chiral porphyrin assemblies are highlighted.The review is mainly divided into two sections:the different strategies for constructing chiral porphyrin assemblies and the applications.The formation of chiral porphyrin assemblies can be from porphyrin molecules substituted with chiral groups;achiral porphyrins induced by chiral additives and spontaneous deracemizations of achiral porphyrins during the assemblies.We also provide an overview of the applications of chiral porphyrin assemblies in chiral sensing,asymmetry catalysis,circularly polarized luminescence,and so on.The further challenge in the field is discussed.
维普期刊数据库