Promoting Effect of ZnO on the Catalytic Performance of CoZSM-5 for CO_(2)-Assisted Dehydrogenation of Ethane

作     者：HE Huan ZOU Zhengxi HUA Weiming YUE Yinghong GAO Zi HE Huan;ZOU Zhengxi;HUA Weiming;YUE Yinghong;GAO Zi

作者机构：Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsDepartment of ChemistryFudan UniversityShanghai 200433P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2023年第39卷第6期

页      面：1064-1069页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(No.22072027) the Fund of the Science&Technology Commission of Shanghai Municipality,China(No.19DZ2270100) 

主　　题：Ethane dehydrogenation CO_(2)utilization ZnO CoZSM-5 Coupling 

摘      要：Aseries of ZnO-modified cobaltous ion exchanged ZSM-5 catalysts is prepared using incipient wetness impregnation and characterized by X-ray diffraction(XRD),N2 adsorption,transmission electron microscopy(TEM),UV-Vis diffuse reflectance spectroscopy(DR UV-Vis),X-ray photoelectron spectroscopy(XPS),pyridine-adsorbed Fourier transform infrared(Py-IR)and *** catalytic performance towards CO_(2)-assisted dehydrogenation of ethane to ethylene has been *** addition of ZnO onto CoZSM-5 obviously improved the yield of ethylene as well as the conversion of CO_(2).The promoting effect is attributed to the good activity of ZnO for the reverse water gas shift(RWGS)reaction,which enhances the coupling between RWGS and ethane dehydrogenation.