Construction of metal chalcogenolate cluster linked organic frameworks

作     者：Zhongqi Wu Qian-Feng Zhang Chao Xu Zhongqi Wu;Qian-Feng Zhang;Chao Xu

作者机构：Institute of Molecular Engineering and Applied ChemistryAnhui University of TechnologyMa'anshan243002PR China Division of Nanotechnology and Functional MaterialsDepartment of Materials Science and EngineeringÅngström LaboratoryUppsala UniversityUppsala75121Sweden 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2023年第42卷第8期

页      面：4-7页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the ÅForsk grant and the Anhui Provincial Natural Science Foundation(2108085QB72) 

主　　题：typically structure cluster 

摘      要：Metal chalcogenide/chalcogenolate clusters(MCCs)are nanoclusters composed of metal and chalcogen ligands,typically containing several to hundreds of metal and chalcogen atoms[1-4].Within these structures,chalcogen ligands(RE^(-)or E^(2-),where R=organic group and E=S,Se,Te)can adopt a variety of bridging coordination modes that connect metal centers into nanoscale *** typically have a well-defined crystal structure,allowing for the study of the structure-properties relationships at the atomic and molecular ***,they usually exhibit unique physicochemical properties that differ from their bulk *** example,the electronic structure and optical properties of MCCs can be precisely tuned by controlling their molecular size,core structure,peripheral organic ligands,and spatial arrangement[5-8].As a result,MCCs are promising materials for applications in energy conversion,sensing,luminescence,and photocatalysis[9-12].