Synthesis and Reactivity of Trifluoromethylthiophosphonium Salts
作者机构：Key Laboratory of Organofluorine ChemistryShanghai Institute of Organic ChemistryUniversity of Chinese Academy of SciencesChinese Academyof Sciences345 LinglingLuShanghai 200032China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2023年第41卷第21期
页 面：2779-2787页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学]
基 金：This work was supported by the National Natural Science Foundation of China(21991121,22271298) the National Key Research and Development Program of China(2021YFF0701700)
主 题：Phosphonium salts Fluorine Rearrangement Trifluoromethylthiolation Synthetic methods
摘 要：This article described an unprecedented synthesis of trifluoromethylthiophosphonium salts from allyl trifluoromethyl sulfoxide and phosphines in the presence of trimethylsilyl trifluoromethanesulfonate(TMSOTf)through Mislow-Evans-type *** resulting trifluoromethylthiophosphonium salts were firstly isolated and fully *** fluoroalkylphosphonium salts,as exemplified by trifluoromethylthio triphenylphosphonium salt(6a),exhibited unique and versatile reaction with nucleophiles and deoxygenative trifluoromethylthiolation reaction of carboxylic ***,the photoredox catalytic tunable radical hydrotrifluoromethylation and hydrotrifluoromethythiolation of unactivated alkenes with 6a was successfully.
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