Controlling assembly-induced symmetry-breaking by tuning the vortex-responsive nanostructures
作者机构：CAS Key Laboratory of Nanosystem and Hierarchical FabricationNational Center for Nanoscience and Technology(NCNST)Beijing 100190China University of Chinese Academy of SciencesBeijing 100049China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2023年第16卷第12期
页 面：13450-13456页
核心收录：
学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学]
基 金：supported by the National Natural Science Foundation of China(Nos.52173159 and 92256304) the Beijing Municipal Science and Technology Commission(No.JQ21003) the National Key R&D Program of the Ministry of Science and Technology of the People’s Republic of China(No.2021YFA1200303)
主 题：supramolecular polymer symmetry-breaking chirality assembly vortex
摘 要：The generation of chirality in supramolecular structures from achiral building blocks has remained a challenge for a long *** this study,we present a vortex-assisted chiral supramolecular polymerization from a series of achiral C3-symmetric monomers,where the mechanism of symmetry-breaking is systematically *** increasing the supersaturation,at the early stage of nucleation and growth,highly ordered assemblies can be generated as the initial chiral ***,chiral assemblies from high supersaturation are hard to interwind into clusters,where clusters as nuclei are not conducive to being fractured by sheer force of vortex ***,it is concluded that chiral assemblies in the nucleation stage possess low energy barrier,so that chiral nuclei could be fractured and replicated by the *** enlarging the initial chiral bias,the major chiral nuclei can evolute into the final chiral polymers.
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