One-Pot Synthesis of Axially and Centrally Chiral A-type Nanogrids
作者机构：Centrefor Molecular Systems and Organic Devices(CMSOD@IAM)State Key Laboratory of Organic Electronics and Information Displays&Institute of Advanced Materials(IAM)Nanjing University of Posts&Telecommunications9 Wenyuan RoadNanjingJiangsu 210023China Frontiers Science Centerfor Flexible Electronics(FSCFE)MIT Key Laboratory of Flexible Electronics(KLoFE)Northwestern Poly-technical UniversityXi'anShaanxi710072China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2023年第41卷第22期
页 面：2969-2974页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：supported by the National Natural Science Foundation of China(22071112 and 22275098) the Project of State Key Laboratory of Organic Electronics and Information Displays,Nanjing University of Posts and Telecommunications(GDX2022010005 and GZR2022010011)
主 题：Friedel-Crafts gridization A-type nanogrids OFET Chirality Nanostructures Organic chemistry
摘 要：A novel type of A-type nanogrids(AGs)with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives,yielding 9%-30%.Additionally,the effect of stereoisomers of 1,1 -binaphthyl difluorenols(BINDFOH)was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than ***,tests on OFET memory devices showed that AGs have a larger storage window,indicating potential for data storage applications.
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