Improving physical properties of poly(vinyl alcohol)/montmorillonite nanocomposite hydrogels via the Hofmeister effect
作者机构:Department of PhysicsResearch Institute for Biomimetics and Soft MatterFujian Provincial Key Laboratory for Soft Functional Materials ResearchXiamen UniversityXiamen 361005China National Institute for Data Science in Health and MedicineXiamen UniversityXiamen 361102China
出 版 物:《Chinese Physics B》 (中国物理B(英文版))
年 卷 期:2023年第32卷第8期
页 面:6-14页
核心收录:
学科分类:081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术]
基 金:Project supported by the National Natural Science Foundation of China(Grant No.12274356) the Fundamental Research Funds for the Central Universities(Grant No.20720220022) the 111 Project(Grant No.B16029)
主 题:nanocomposite hydrogels Hofmeister effect network structure poly(vinyl alcohol) montmorillonite
摘 要:Hydrogel is a kind of three-dimensional crosslinked polymer material with high moisture ***,due to the network defects of polymer gels,traditional hydrogels are usually brittle and fragile,which limits their practical ***,we present a Hofmeister effect-aided facile strategy to prepare high-performance poly(vinyl alcohol)/montmorillonite nanocomposite *** montmorillonite nanosheets can not only serve as crosslinking agents to enhance the mechanical properties of the hydrogel but also promote the ion *** importantly,based on the Hofmeister effect,the presence of(NH_(4))_(2)SO_(4)can endow nanocomposite hydrogels with excellent mechanical properties by affecting PVA chains aggregation state and *** a result,the as-prepared nanocomposite hydrogels possess unique physical properties,including robust mechanical and electrical *** as-prepared hydrogels can be further assembled into a high-performance flexible sensor,which can sensitively detect large-scale and small-scale human *** simple design concept of this work is believed to provide a new prospect for developing robust nanocomposite hydrogels and flexible devices in the future.