Beef and cone-in-cone calcite fibrous cements associated with the end-Permian and end-Triassic mass extinctions： Reassessment of processes of formation

作     者：Stephen Kershaw Li Guo 

作者机构：Department of Life Sciences Brunel Uniuersity Kingston Lane Uxbridge Middlesex UB8 3PH UK CASP University of Cambridge 181a Huntingdon Road CB3 0DH Cambridge UK 

出 版 物：《Journal of Palaeogeography》 (古地理学报（英文版）)

年 卷 期：2016年第5卷第1期

页      面：28-42页

核心收录：

学科分类：070903[理学-古生物学与地层学(含：古人类学)] 0709[理学-地质学] 07[理学] 

主　　题：End Permian mass extinction End Triassic mass extinctionBeefCone in cone calciteOcean acidification 

摘      要：This paper reassesses published interpretation that beef and cone-in-cone （B-CIC） fibrous calcite cements were precipitated contemporaneously just below the sea floor in uncon- solidated sediment, in limestones associated with the end-Permian （P/T） and end-Triassic （T/J） mass extinctions. That interpretation introduced the concept of a sub-seafloor car- bonate factory associated with ocean acidification by raised carbon dioxide driven by volcanic eruption, coinciding with mass extinction. However, our new fieldwork and petrographic analysis, with literature comparison, reveals several problems with this concept. Two key points based on evidence in the T/J transition of the UK are： （I） that B-CIC calcite deposits form thin scattered layers and lenses at several horizons, not a distinct deposit associated with volcanic activity; and （2） B-CIC calcite is more common in Early Jurassic sediments after the extinction and after the end of the Central Atlantic Magmatic Province volcanism proposed to have supplied the carbon dioxide required. Our samples from Late Triassic, Early Jurassic and Early Cretaceous limestones in southern UK show that B-CIC calcite occurs in both marine and non-marine sediments, therefore ocean processes are not mandatory for its formation. There is no proof that fibrous calcite was formed before lithification, but our Early Jurassic samples do prove fibrous calcite formed after compaction, thus interpretation of crystal growth in uncon- solidated sediment is problematic. Furthermore, B-CIC crystals mostly grew both upwards and downwards equally, contradicting the interpretation of the novel carbonate factory that they grew preferentially upwards in soft sediment. Finally, Early Jurassic and Early Cretaceous examples are not associated with mass extinction. Three further key points derived from the literature include： （I） B-CIC calcite is wide- spread geographically and stratigraphically, not clustered around mass extinctions or the Paleocene-E