Arsenic retention and transport behavior in the presence of typical anionic and nonionic surfactants

作     者：Chuan Liang Xianliang Wang Xianjia Peng 

作者机构：State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Institute of Environmental Health and Related Product Safety Chinese Centre for Disease Control and Prevention State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental Sciences 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2016年第28卷第1期

页      面：249-258页

核心收录：

学科分类：083001[工学-环境科学] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 

基　　金：supported by the National Natural Science Foundation of China (No. 41273123) the special fund from the State Key Joint Laboratory of Environment Simulation and Pollution Control (Research Center for Eco-environmental Sciences, Chinese Academy of Sciences) (No. 14Z02ESPCR) 

主　　题：Surfactants Arsenic Retention Transport 

摘      要：The massive production and wide use of surfactants have resulted in a large amount of surfactant residuals being discharged into the environment,which could have an impact on arsenic *** the present study,the influence of the anionic surfactant sodium dodecyl benzene sulfonate（SDBS） and nonionic surfactant polyethylene glycol octylphenyl ether（Triton X-100） on arsenic behavior was investigated in batch and column *** presence of SDBS and Triton X-100 reduced arsenic retention onto ferrihydrite（FH）,enhanced arsenic transport through FH coated sand（FH-sand） columns and promoted arsenic release from the FH *** coexisting surfactants in solution,the equilibrium adsorbed amount of arsenic on FH decreased by up to 29.7% and the adsorption rate decreased by up to 52.3%.Pre-coating with surfactants caused a decrease in the adsorbed amount and adsorption rate of arsenic by up to 15.1% and 58.3%,*** of the adsorption attenuation caused by surfactants,breakthrough of As（Ⅴ） and As（Ⅲ） with SDBS in columns packed with FH-sand was 23.8% and 14.3%faster than that in those without SDBS,*** columns packed with SDBS-coated FH-sand,transport of arsenic was enhanced to a greater *** of As（Ⅴ） and As（Ⅲ） was 52.4% and 43.8% faster and the cumulative retention amount was 44.5% and 57.3% less than that in pure FH-sand column systems,*** of arsenic by surfactants increased with the increase of the initial adsorbed amount of *** cumulative release amount of As（Ⅴ） and As（Ⅲ） from the packed column reached 10.8% and 36.0%,respectively.