N-Aryl diketopyrrolopyrrole derivatives towards organic optical and electronic materials
作者机构:State Key Laboratory of Applied Organic Chemistry(SKLAOC)Key Laboratory of Special Function Materials and Structure DesignCollege of Chemistry and Chemical EngineeringLanzhou UniversityLanzhou 730000China Beijing National Laboratory for Molecular SciencesCAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical SciencesUniversity of Chinese Academy of SciencesBeijing 100049China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2023年第34卷第6期
页 面:157-163页
核心收录:
学科分类:07[理学] 08[工学] 070303[理学-有机化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
基 金:the financial support from National Natural Science Foundation of China(NSFC,Nos.22175081 and 21833005) Beijing National Laboratory for Molecular Sciences(No.BNLM202010) State Key Laboratory of Physical Chemistry of Solid Surfaces(No.202108) Guangdong Provincial Key Laboratory of Catalysis(No.20210701)。
主 题:Diketopyrrolopyrrole N-arylation π-expanded derivatives Organic optical material Organic electronic material
摘 要:Diketopyrrolopyrrole(DPP)and related derivatives have drawn great attention due to their applications in organic optical/electronic materials.Progress in these materials is associated with developments in the syntheses of the DPP family.Chemical modification of DPP at nitrogen atom,including N-alkylation and N-arylation,is an effective strategy to improve its physical and chemical properties,such as solubility,optical and semiconducting properties.However,N-arylation of DPPs remains challenging compared to the easily accessible N-alkylation.Herein,the synthesis of N-aryl DPP derivatives and correlatedπ-expanded DPPs are summarized,and their optical/electronic properties are introduced.The future perspectives of N-aryl DPP derivatives are also discussed.