Metal-organic frameworks based single-atom catalysts for advanced fuel cells and rechargeable batteries

作     者：Yifei Wu Peng Hu Fengping Xiao Xiaoting Yu Wenqi Yang Minqi Liang Ziwei Liang Aixin Zhu Yifei Wu;Peng Hu;Fengping Xiao;Xiaoting Yu;Wenqi Yang;Minqi Liang;Ziwei Liang;Aixin Zhu

作者机构：College of Chemistry and Chemical EngineeringYunnan Normal UniversityKunming 650500YunnanChind School of Energy and Environment ScienceYunnan Normal UniversityKunming 650500.YunnanChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)Nankai UniversityTianjin 300071China School of Environment and Chemical EngineeringZhaoqing UniversityZhaoqing 526061GuangdongChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第80卷第5期

页      面：501-534,I0012页

核心收录：

学科分类：0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Financial support was provided by the Guangdong College Students’Innovative Project(202110580014) the Guangdong “Climbing”Program for Research Items(pdjh2021b0544)。 

主　　题：Metal-organic frameworks Single-atom catalysts Rechargeable batteries Electrocatalysts Coordination configuration 

摘      要：The next-generation energy storage systems such as fuel cells,metal-air batteries,and alkali metal(Li,Na)-chalcogen(S,Se)batteries have received increasing attention owing to their high energy density and low cost.However,one of the main obstacles of these systems is the poor reaction kinetics in the involved chemical reactions.Therefore,it is essential to incorporate suitable and efficient catalysts into the cell.These years,single-atom catalysts(SACs)are emerging as a frontier in catalysis due to their maximum atom efficiency and unique reaction selectivity.For SACs fabrication,metal-organic frameworks(MOFs)have been confirmed as promising templates or precursors due to their high metal loadings,structural adjustability,porosity,and tailorable catalytic site.In this review,we summarize effective strategies for fabricating SACs by MOFs with corresponding advanced characterization techniques and illustrate the key role of MOFs-based SACs in these batteries by explaining their reaction mechanisms and challenges.Finally,current applications,prospects,and opportunities for MOFs-based SACs in energy storage systems are discussed.