REACTIONS OF C_(60) WITH R_3SnH: A NEW SYNTHETIC TO C_(60)(RH)n AND THE PROPERTY OF C_(60) TO CATALYZE RADICAL REACTIONS

作     者：She Y.M. Tu Y.P. Guo X.H. Liu Z.Y. Liu S.Y. 

作者机构：Changchun Inst. of Applied Chemistry Chinese Academy of Sciences Changchun 130022 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1996年第7卷第5期

页      面：433-436页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

主　　题：CHEMISTRY C60 FULLERENES 

摘      要：Abstract: A new method for the preparation of polyakyl and polyarenefullerene derivatives C60(RH)n (R=Bu,n=1-3; R=Ph,n=1-10) by the reaction of C60 with organotin hydride in toluene is described. Another series of products of stannanes RaSnbHc (B=Ru, a=3-8, b=1-4, c=0-3; R=Ph.a=3-11, b=1-5, e=0-4) were also obtained which shows that C60 can catalyze polymerization of organic-tin. These products were detenrmined by mass and infrared spectromeny. And the possible reaction mechanisms are discussed.