REACTIONS OF C_(60) WITH R_3SnH: A NEW SYNTHETIC TO C_(60)(RH)n AND THE PROPERTY OF C_(60) TO CATALYZE RADICAL REACTIONS
REACTIONS OF C60 WITH R3SnH: A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS作者机构:Changchun Inst. of Applied Chemistry Chinese Academy of Sciences Changchun 130022
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1996年第7卷第5期
页 面:433-436页
核心收录:
学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
主 题:CHEMISTRY C60 FULLERENES
摘 要:Abstract: A new method for the preparation of polyakyl and polyarenefullerene derivatives C60(RH)n (R=Bu,n=1-3; R=Ph,n=1-10) by the reaction of C60 with organotin hydride in toluene is described. Another series of products of stannanes RaSnbHc (B=Ru, a=3-8, b=1-4, c=0-3; R=Ph.a=3-11, b=1-5, e=0-4) were also obtained which shows that C60 can catalyze polymerization of organic-tin. These products were detenrmined by mass and infrared spectromeny. And the possible reaction mechanisms are discussed.