Reductive Cleavage of S-S Bond by Sm/NiCl_2 or Sm/NiCl_2·6H_2O System: A New Method for the Preparation of Thiolesters

作     者：Hua Yue WU Red Er CHEN Yong Min ZHANG(Department of Cheniistry, Wenzhou Normal College, Wenzhou, 325000)(Departnieni of Chemistry. Zhejiang University at Xixi Campus, Hangzhou, 310028) 

作者机构：Department of Chemistry Wenzhou Normal College Wenzhou 325000 China Department of Chemistry Zhejiang University at Xixi Campus Hangzhou 310028 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1999年第10卷第11期

页      面：899-902页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

主　　题：Samarium-nickel (II) chloride. disulfide thiolester. 

摘      要：Disulfides were reduced by the Sm/NiCl2 or Sin/NiCI_2 6H_2O system to generate thiolateanion. which reacted further with anhydrides or acyl chlorides to afford thiolesters in good yieldsunder mild and neutral conditions.