Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst
Efficient oxidation of benzyl alcohol with heteropolytungstate as reaction-controlled phase-transfer catalyst作者机构：Department of Polymer Science and Materials Dalian University of Technology Liaoning Research Center of High Performance Resin Engineering and Technology Dalian 116012 China
出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)
年 卷 期：2007年第18卷第8期
页 面：936-938页
核心收录：
学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：National High-tech Research and Development Program (2003AA33G030)
主 题：Heteropolytungstate Reaction-controlled phase-transfer Benzyl alcohol Benzaldehyde Hydrogen peroxide
摘 要：A series of heteropolytungstates has been synthesized and utilized as catalysts to catalyze oxidation of benzyl alcohol with aqueous hydrogen peroxide. The results indicated that three of these catalysts showed the properties of reaction-controlled phasetransfer catalysis, and they had excellent catalytic ability to the oxidation of benzyl alcohol. No other by-products were detected by gas chromatography. Once the hydrogen peroxide was consumed completely, the catalyst precipitated from solvent, and the results of the catalyst recycle showed that the catalyst had high stability.
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