Photoinduced RAFT Step-Growth Polymerization toward Degradable Living Polymer Networks

作     者：Zhuang Li Jiajia Li Bowen Zhao Xiaofeng Pan Xiangqiang Pan Jian Zhu Zhuang Li;Jiajia Li;Bowen Zhao;Xiaofeng Pan;Xiangqiang Pan;Jian Zhu

作者机构：State and Local Joint Engineering Laboratory for Novel Functional Polymeric MaterialsJiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationDepartment of Polymer Science and EngineeringCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhouJiangsu 215123China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2023年第41卷第5期

页      面：503-508页

核心收录：

学科分类：07[理学] 070305[理学-高分子化学与物理] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(No.22101196) the China Postdoctoral Science Foundation(No.2021M692348) the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions and the Program of Innovative Research Team of Soochow University. 

主　　题：RAFT step-growth polymerization Single unit monomer insertion Radical reactions Ene reaction Polymers 

摘      要：The application of reversible degenerative radical polymerization(RDRP)in the construction of polymer networks(PNs)provides a facile and convenient way to fabricate 3D objects with the ability to be posttransformed.However,the polymerization mechanism mainly relies on chain-growth polymerization,which limits its wide application for various polymeric materials with different functionalities.