Design and Synthesis of Al_(7)Ni_(2) Heterometallic Clusters Based on Metal Substitution and Ligands Protection Strategies

作     者：Ya-Jie Liu Li-Min Cui Wei-Hui Fang Jian Zhang Ya-Jie Liu;Li-Min Cui;Wei-Hui Fang;Jian Zhang

作者机构：State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouFujian 350002China University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2023年第41卷第5期

页      面：521-526页

核心收录：

学科分类：07[理学] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work is supported by the National Natural Science Foundation of China(92061104,21935010 and 21973096) the Natural Science Foundation of Fujian Province(2021J06035) the Youth Innovation Promotion Association CAS(Y2018081). 

主　　题：Cluster compounds Heterometallic complexes Crystal engineering Catalytic properties Aluminum oxo cluster Aluminum 

摘      要：The synthesis of heterometallic aluminum-based materials is challenging yet attractive,due to their potential applications in optics,catalysis,magnetism and semiconductor device.We have now successfully synthesized two Al,Niz heterometallic clusters bearing different peripheral alkoxide ligands through a heterometal substitution strategy.