Electrocatalytic oxidation of 5-hydroxymethylfurfural for sustainable 2,5-furandicarboxylic acid production-From mechanism to catalysts design

作     者：Xiaoli Jiang Wei Li Yanxia Liu Lin Zhao Zhikai Chen Lan Zhang Yagang Zhang Sining Yun 

作者机构：School of Materials and EnergyUniversity of Electronic Science and Technology of ChinaChengduChina State Key Laboratory of Electronic Thin Films and Integrated DevicesUniversity of Electronic Science and Technology of ChinaChengduChina Univ LyonCNRSINSA-LyonUniversite Claude Bernard Lyon 1VilleurbanneFrance School of Materials Science and EngineeringXi’an University of Architecture and TechnologyXi’anChina 

出 版 物：《SusMat》 (可持续发展材料（英文）)

年 卷 期：2023年第3卷第1期

页      面：21-43页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：University of Electronic Science and Technology of China,Grant/Award Number:A1098531023601208 Scientific Research Foundation,Grant/Award Number:Y030212059003045 China Postdoctoral Science Foundation,Grant/Award Numbers:2021TQ0059,2022M710610 National Natural Science Foundation of China,Grant/Award Numbers:21464015,21472235 

主　　题：5-hydroxymethylfurfural catalysts design strategies electrocatalytic oxidation pairing reactions reaction mechanism 

摘      要：Catalytic conversion of biomass-based platform chemicals is one of the significant approaches to utilize renewable biomass resources.2,5-Furandicarboxylic acid(FDCA),obtained by an electrocatalytic oxidation of 5-hydroxymethylfurfural(HMF),has attracted extensive attention due to the potential of replacing terephthalic acid to synthesize high-performance polymeric materials for *** the present work,the pHdependent reaction pathways and factors influencing the degree of functional group oxidation are first *** the reaction mechanism of HMF oxidation is further elucidated using the representative *** addition,the emerging catalyst design strategies(defects,interface engineering)used in HMF oxidation are generalized,and structure-activity relationships between the abovementioned strategies and catalysts performance are ***,cathode pairing reactions,such as hydrogen evolution reaction,CO_(2) reduction reaction(CO_(2)RR),oxygen reduction reaction,and thermodynamically favorable organic reactions to lower the cell voltage of the electrolysis system,are ***,the challenges and prospects of the electrochemical oxidation of HMF for FDCA are presented,focusing on deeply investigated reaction mechanism,coupling reaction,reactor design,and downstream product separation/purification.