Chiral Discrimination in N-(O, O-dialkyl)phosphoamino Acid Monolayers at the Air-water Interface

作     者：Ning XU Zhou ZHOU Hong Mei WANG Chang Hui DENG Yan Mei LI Yu Fen ZHAO Ling Xuan WANG Tian Kai LI 

作者机构：Bioorg.Phosph.Chem.LabDepartment of ChemistryTsinghua UniversityBeijing 100084 Institute of Photographic ChemistryChinese Academy of SciencesBeijing 100101 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2000年第11卷第8期

页      面：717-718页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：chiral discrimination N-(O,O-dialkyl)phosphoamino acid monolayer 

摘      要：In this paper, chiral discrimination in N-(O,O-dialkyl)phosphoamino acid monolayers at the air/water interface was studied and it was revealed that the D:L=1:1 racemic monolayer of N-(O, O-dihexadecyl)phosphoalanine is packed more densely in solid phase while shows a higher LE to LC transition pressure than the enantiomeric ones.