Visible Light-Driven Catalyst-Free Amination of Indoles Initiated by Electron Donor-Acceptor Complexes
作者机构：School of Life Science and Engineering Sichuan Engineering Research Center for Biomimetic Synthesis of Natural Drugs Southwest Jiaotong University Chengdu Sichuan 610031 China Department of Pharmacy Sichuan Academy of Medical Science & Sichuan Provincial People's Hospital/Personalized Drug Therapy Key Laboratory of Sichuan Province School of Medicine University of Electronic Science and Technology of China Chengdu Sichuan 610072 China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2023年第41卷第12期
页 面：1485-1490页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：financial support from the National Natural Science Foundation of China(Grant Nos.21901216 and 82074003,82174083) the Funds of Sichuan Science and Technology Program(23NSFSC0862,2021YFSY0041,2021YFH0064 and 2021ZHFP0032) the Opening subject under KF-202204 in the State Key Laboratory of Pharmaceutical Biotechnology,Nanjing University,China,the Fund of Science and Technology Agency of Chengdu(2019-YF09-00049-SN) the research project of the Administration of Traditional Chinese Medicine of Sichuan(2021MS110) the Open Project Program of Irradiation Preservation Technology Key Laboratory of Sichuan Province,Sichuan Institute of Atomic Energy(No.FZBC2020002) the Fundamental Research Funds for the Central Universities(2682020ZT85)
主 题：Photochemistry Amination C-N bond formation Green chemistry N-Heterocycles Donor-acceptor systems
摘 要：The visible light-driven C2 or C3 amination of indoles without any additives was initiated via electron donor-acceptor (EDA) complex formed by indole and N-aminopyridinium *** method was compatible with a wide range of substrates and could proceed smoothly without the addition of any photocatalysts,transition-metal catalysts,or bases.A variety of studies were carried out to examine the presence of EDA complex.
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