Quantum hydrogen tunneling promoting halogen-atom and group transfer chemistry

作     者：Xiao Xiao Yi-Ping Yao Biao Chen Chuan Xiang Alvin Tan Fen-Er Chen 

作者机构：Institute of Pharmaceutical Science and TechnologyCollaborative Innovation Center of Yangtze River Delta Region Green PharmaceuticalsZhejiang University of TechnologyHangzhou 310014China Department of ChemistryNational University of Singapore3 Science Drive 3117543Singapore Engineering Center of Catalysis and Synthesis for Chiral MoleculesFudan UniversityShanghai 200433China Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral DrugsShanghai 200433China 

出 版 物：《绿色合成与催化(英文)》 (Green Synthesis and Catalysis)

年 卷 期：2023年第4卷第3期

页      面：187-189页

学科分类：0710[理学-生物学] 0831[工学-生物医学工程（可授工学、理学、医学学位）] 081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0703[理学-化学] 0836[工学-生物工程] 

基　　金：supported by the National Natural Science Foundation of China(No.22208302) the Natural Science Foundation of Zhejiang Province of China(Nos.LQ21B020006 and ZJ2022039) 

主　　题：Quantum hydrogen tunneling Halogen-atom and group transfer Carbon radicals Substituted cyclohexadiene Photocatalysis 

摘      要：A quantum-hydrogen-tunneling-controlled halogen-atom and group transfer strategy has been successfully developed to generate carbon radicals by using the substituted cyclohexadiene as the abstractor under mild photochemical conditions,in which alkyl and aryl halides as well as numerous alcohol and thiol analogues can be *** investigation unveiled that this process is inhibited from thermodynamic and kinetic effects but is rendered successful through quantum tunneling.