Enhanced H_(2) permeation and CO_(2) tolerance of self-assembled ceramic-metal-ceramic BZCYYb-Ni-CeO_(2) hybrid membrane for hydrogen separation

作     者：Jianqiu Zhu Jingzeng Cui Yuxuan Zhang Ze Liu Chuan Zhou Susu Bi Jingyuan Ma Jing Zhou Zhiwei Hu Tao Liu Zhi Li Xiangyong Zhao Jian-Qiang Wang Linjuan Zhang Jianqiu Zhu;Jingzeng Cui;Yuxuan Zhang;Ze Liu;Chuan Zhou;Susu Bi;Jingyuan Ma;Jing Zhou;Zhiwei Hu;Tao Liu;Zhi Li;Xiangyong Zhao;Jian-Qiang Wang;Linjuan Zhang

作者机构：Key Laboratory of Interfacial Physics and TechnologyShanghai Institute of Applied PhysicsChinese Academy of SciencesShanghai 201800China Key Laboratory of Optoelectronic Material and DeviceDepartment of PhysicsShanghai Normal UniversityShanghai 200234China State Key Laboratory of Materials-Oriented Chemical EngineeringCollege of Chemical EngineeringNanjing Tech UniversityNanjing 211816JiangsuChina Shanghai Synchrotron Radiation FacilityZhangjiang LaboratoryShanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Max Planck Institute for Chemical Physics of SolidsNöthnitzer Strasse 40Dresden 01187Germany Shandong Energy Group Co.Ltd.Jinan 250014ShandongChina University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第82卷第7期

页      面：47-55,I0002页

核心收录：

学科分类：080706[工学-化工过程机械] 08[工学] 0807[工学-动力工程及工程热物理] 

基　　金：financially supported by the National Key R&D Program of China(2021YFA1502400) the"Transformational Technologies for Clean Energy and Demonstration" the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA2100000) the National Natural Science Foundation of China(52172005,21905295,22179141) the DNL Cooperation Fund,CAS(DNL202008) the Photon Science Center for Carbon Neutrality and the Major Scientific and Technological Innovation Project of Shandong Province(2020CXGC010402) 

主　　题：Hydrogen separation Triple phase hybrid membrane Mixed proton-electron conductor Chemical stability X-ray absorption spectra 

摘      要：Perovskite-type mixed protonic-electronic conducting membranes have attracted attention because of their ability to separate and purify hydrogen from a mixture of gases generated by industrial-scale steam reforming based on an ion diffusion *** cost-effective membrane materials that can achieve both high H_(2) permeability and strong CO_(2)-tolerant chemical stability has been a major challenge for industrial ***,we constructed a triple phase(ceramic-metal-ceramic)membrane composed of a perovskite ceramic phase BaZr_(0.1)Ce_(0.7)Y_(0.1)Yb_(0.1)O_(3-δ)(BZCYYb),Ni metal phase and a fluorite ceramic phase CeO_(2).Under H_(2) atmosphere,Ni metal in-situ exsolved from the oxide grains,and decorated the grain surface and boundary,thus the electronic conductivity and hydrogen separation performance can be *** BZCYYbNi-CeO_(2)hybrid membrane achieved an exceptional hydrogen separation performance of 0.53 mL min^(-1)cm^(-2) at 800℃ under a 10 vol% H_(2) atmosphere,surpassing all other perovskite membranes reported to ***,the CeO_(2) phase incorporated into the BZCYYb-Ni effectively improved the CO_(2)-tolerant chemical *** BZCYYbNi-CeO_(2) membrane exhibited outstanding long-term stability for at least 80 h at 700℃ under 10 vol%CO_(2)-10 vol%H_(2).The success of hybrid membrane construction creates a new direction for simultaneously improving their hydrogen separation performance and CO_(2) resistance stability.