A review on the development of electrolytes for lithiumbased batteries for low temperature applications
作者机构：Department of Chemical and Materials EngineeringUniversity of Nevada−RenoRenoNV 89557USA Department of Chemical and Materials Engineering Nevada Institute for SustainabilityUniversity of Nevada−RenoRenoNV 89557USA
出 版 物：《能源前沿:英文版》 (Frontiers in Energy)
年 卷 期：2023年第17卷第1期
页 面：43-71页
核心收录：
学科分类：0820[工学-石油与天然气工程] 0808[工学-电气工程] 08[工学]
基 金：the National Aeronautics and Space Administration USA(No.80NSSC19M0152).
主 题：electrolyte lithium-ion low temperature aerospace solid-electrolyte interface
摘 要：The aerospace industry relies heavily on lithium-ion batteries in instrumentation such as satellites and land rovers.This equipment is exposed to extremely low temperatures in space or on the Martian surface.The extremely low temperatures affect the discharge characteristics of the battery and decrease its available working capacity.Various solvents,cosolvents,additives,and salts have been researched to fine tune the conductivity,solvation,and solid-electrolyte interface forming properties of the electrolytes.Several different resistive phenomena have been investigated to precisely determine the most limiting steps during charge and discharge at low temperatures.Longer mission lifespans as well as self-reliance on the chemistry are now highly desirable to allow low temperature performance rather than rely on external heating components.As Martian rovers are equipped with greater instrumentation and demands for greater energy storage rise,new materials also need to be adopted involving next generation lithiumion chemistry to increase available capacity.With these objectives in mind,tailoring of the electrolyte with highercapacity materials such as lithium metal and silicon anodes at low temperatures is of high priority.This review paper highlights the progression of electrolyte research for low temperature performance of lithium-ion batteries over the previous several decades.
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