New Method of Predicting the Thermodynamic Properties of Solutions

作     者：Suntsov Yuri Konstantlnovlch 

作者机构：Department of Physical and Analytical Chemistry Voronezh State University of Engineering Technologies ~'oronezh 394000 Russia 

出 版 物：《Journal of Chemistry and Chemical Engineering》 (化学与化工（英文版）)

年 卷 期：2014年第8卷第3期

页      面：306-314页

学科分类：080701[工学-工程热物理] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Vapor-liquid equilibrium Helmholtz energy enthalpy entropy of solutions equation of state. 

摘      要：Thermodynamic functions solutions of a 25 binary systems formed n-alcohols and esters of aliphatic acids by were calculated using the standards ideal solution and ideal gas. The value change regularity of the thermodynamic functions of solutions depending on their molar mass and concentration of the solutions＇ components was determined by the thermodynamic analysis. The method of prediction of the thermodynamic properties of binary solutions was suggested on the basis of the determined regularities. The corresponding equations were obtained.