Sn-doped BiOCl nanosheet with synergistic H^(+)/Zn^(2+)co-insertion for“rocking chair”zinc-ion battery

作     者：Yuzhu Qian Hongrui Wang Xinni Li Ting Song Yong Pei Li Liu Bei Long Xiongwei Wu Xianyou Wang Yuzhu Qian;Hongrui Wang;Xinni Li;Ting Song;Yong Pei;Li Liu;Bei Long;Xiongwei Wu;Xianyou Wang

作者机构：School of ChemistryXiangtan UniversityXiangtan 411105HunanChina School of Chemistry and Materials ScienceHunan Agricultural UniversityChangsha 410128HunanChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第81卷第6期

页      面：623-632,I0014页

核心收录：

学科分类：0808[工学-电气工程] 081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：supported by the Natural Science Foundation of China (52102312,51672234,and 52072325) the Natural Science Foundation of Hunan Province of China (2021JJ40528) the China Postdoctoral Science Foundation (2020M682581) the Macao Young Scholars Program (AM2021011) the College Student Innovation and Entrepreneurship Training Program (S202210530051) 

主　　题：Sn-doped BiOCl nanosheet High mass loading anode Synergistic H^(+)/Zn^(2+)co-insertion Fast ionic/electronic diffusion “Rocking chair”zinc-ion battery 

摘      要：The development of insertion-type anodes is the key to designing“rocking chairzinc-ion ***,there is rare report on high mass loading anode with high ***,{001}-oriented Bi OCl nanosheets with Sn doping are proposed as a promising insertion-type *** designs of cross-linked CNTs conductive network,{001}-oriented nanosheet,and Sn doping significantly enhance ion/electron transport,proved via experimental tests and theoretical calculations(density of states and diffusion barrier).The H^(+)/Zn^(2+)synergistic co-insertion mechanism is proved via ex situ XRD,Raman,XPS,and SEM ***,this optimized electrode delivers a high reversible capacity of 194 m A h g^(-1)at 0.1 A g^(-1)with a voltage of≈0.37 V and an impressive cyclability with 128 m A h g^(-1)over 2500 cycles at 1 A g^(-1).It also shows satisfactory performances at an ultrahigh mass loading of 10 mg cm^(-2).Moreover,the Sn-Bi OCl//MnO_(2)full cell displays a reversible capacity of 85 m A h g^(-1)at 0.2 A g^(-1)during cyclic test.