Two‑Dimensional Mesoporous Materials for Energy Storage and Conversion:Current Status,Chemical Synthesis and Challenging Perspectives

作     者：Jieqiong Qin Zhi Yang Feifei Xing Liangzhu Zhang Hongtao Zhang Zhong‑Shuai Wu 

作者机构：College of ScienceHenan Agricultural University63 Agricultural RoadZhengzhou 450002HenanChina State Key Laboratory of CatalysisDalian Institute of Chemical PhysicsChinese Academy of Sciences457 Zhongshan RoadDalian 116023LiaoningChina University of Chinese Academy of Sciences19 A Yuquan RoadShijingshan DistrictBeijing 100049China 

出 版 物：《Electrochemical Energy Reviews》 (电化学能源评论（英文）)

年 卷 期：2023年第6卷第1期

页      面：614-650页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Jieqiong Qin,Zhi Yang,and Feifei Xing contributed equally to this work.The authors acknowledge the National Natural Science Foundation of China(Nos.22125903,51872283,22109040) Dalian Innovation Support Plan for High Level Talents(2019RT09) DICP(ZZBS201802 and I202032) Dalian National Laboratory For Clean Energy(DNL),CAS,DNL Cooperation Fund,CAS(DNL201912,DNL201915,DNL202016,DNL202019) Top-Notch Talent Program of Henan Agricultural University(30500947) the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy(YLU-DNL Fund 2021002,2021009) 

主　　题：2D materials Mesopores Nanosheets Energy storage Energy conversion 

摘      要：Two-dimensional(2D)mesoporous materials(2DMMs),defined as 2D nanosheets with randomly dispersed or orderly aligned mesopores of 2–50 nm,can synergistically combine the fascinating merits of 2D materials and mesoporous mate-rials,while overcoming their intrinsic shortcomings,e.g.,easy self-stacking of 2D materials and long ion transport paths in bulk mesoporous *** unique features enable fast ion diffusion,large specific surface area,and enriched adsorption/reaction sites,thus offering a promising solution for designing high-performance electrode/catalyst materials for next-generation energy storage and conversion devices(ESCDs).Herein,we review recent advances of state-of-the-art 2DMMs for high-efficiency ESCDs,focusing on two different configurations of in-plane mesoporous nanosheets and sandwich-like mesoporous ***,a brief introduction is given to highlighting the structural advantages(e.g.,tailored chemical composition,sheet configuration,and mesopore geometry)and key roles(e.g.,active materials and functional additives)of 2DMMs for high-performance ***,the chemical synthesis strategies of 2DMMs are summarized,including template-free,2D-template,mesopore-template,and 2D mesopore dual-template ***,the wide applications of 2DMMs in advanced supercapacitors,rechargeable batteries,and electrocatalysis are discussed,enlightening their intrinsic structure–property ***,the future challenges and perspectives of 2DMMs in energy-related fields are presented.