Formation of [3]Pseudorotaxanes from β-cyclodextrin and a Series of Dicarboxylic Acids with Their Corresponding α,ω-alkanedicarboxylate Anions
Formation of Pseudorotaxanes from β-cyclodextrin and a Series of Dicarboxylic Acids with Their Corresponding α,ω-alkanedicarboxylate Anions作者机构：Department of Biochemistry and Engineering Anhui University of Technology and Science Wuhu 241000 China Department of Polymer Science and Engineering University of Science and Technology of China Hefei 230026 China
出 版 物：《Chinese Journal of Chemical Physics》 (化学物理学报（英文）)
年 卷 期：2008年第21卷第4期
页 面：387-392页
核心收录：
学科分类：0832[工学-食品科学与工程（可授工学、农学学位）] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 083201[工学-食品科学]
基 金：Youthful Science Foundation for the Talents of Anhui University of Technology and Science (No. 2006YQQ003) the Natural Science Program of Educational Commission of Anhui Province (No. KJ2008B002) 国家自然科学基金
主 题：β-cyclodextrin Inclusion complex Dicarboxylic acid α ω-alkanedicarboxylate anion
摘 要：Inclusion complexes between β-cyclodextrin （β-CD） and a series of dicarboxylic acids （DAn, n=11-15） were prepared by co-grinding and co-precipitation methods and the [3]pseudorotaxane structure of them was elucidated by FTIR, DTA and XRD characterizations. Inclusion complexes of β-CD and α,ω-alkanedicarboxylate anions （DAn^2-） were acquired by neutralizing β-CD/DAn different inclusion complexes with sodium hydroxide and the structure was also proved to be a pseudorotaxane structure by ^1H-NMR spectra and NOESY spectrum. Both the inclusion complexes of β-CD/DAn and β-CD/DAn^2- adopt the [3]pseudorotaxane structure with β-CD arranged in dimers threaded onto one aliphatic chain and the binding mode of 1：1 inclusion complex was excluded based on the consideration of chain conformations.
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