Hydrothermal Synthesis and Crystal Structure of a Cobalt(Ⅱ) Polymer with One-dimensional Chain Structure: [Co(phen)(BDC)(H_2O)]_n·0.5nH_2BDC

作     者：LIU Bo LI Xiu-Mei CUI Yun-Cheng FENG Ming 

作者机构：Department of Chemistry Jilin Normal University Siping Jilin 136000 China Department of Chemistry Tonghua Teachers College Tonghua Jilin 134002 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2007年第26卷第2期

页      面：184-188页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：The project was supported by the Education Office of Jilin Province (No. 0047) 

主　　题：hydrothermal synthesis crystal structure coordination polymer 

摘      要：A metal-organic coordination polymer [Co（phen）（BDC）（H20）]n·0.5nH2BDC （H2BDC = terephthahc acid, phen = 1,10-phenanthrohne） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The complex crystallizes in triclinic, space group Pi with a = 9.771（3）, b =10.739（3）, c = 11.249（4）A, α = 75.946（3）, β = 65.306（3）, γ = 86.073（4）°, V = 1039.6（6）A^3, C24H17CON2O7, Mr= 504.33, Dc = 1.611 g/cm^3,μ（MoKα） = 0.878 mm^-1, F（000） = 516, Z= 2, the final R = 0.0547 and wR = 0.1138 for 2916 observed reflections （I 〉 2σ（I））. It exhibits a one-dimensional zigzag chain-like structure.