Atomically Dispersed Metals on Nanodiamond-Derived Hybrid Materials for Heterogeneous Catalysis

作     者：Fei Huang Mi Peng Hongyang Liu Ding Ma 

作者机构：Shenyang National Laboratory for Materials ScienceInstitute of Metal ResearchChinese Academy of SciencesShenyang 110016P.R.China Beijing National Laboratory for Molecular EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871P.R.China 

出 版 物：《Accounts of Materials Research》 (材料研究述评（英文）)

年 卷 期：2023年第4卷第3期

页      面：223-236页

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Key R&D Program of China(2022 YFA 1504500,2022YFB4003100,2021YFA1502802) the National Natural Science Foundation of China(22202213,22072162,92145301,U21B2092,21961160722,91845201,22202004) the Chinese Academy of Sciences(172GJHZ2022028MI) the Dalian National Lab for Clean Energy(DNL Cooperation Fund 202001) the Science and Technology Program of Sichuan Province(2021YFSY0021) the China Petroleum&Chemical Corporation(No.420043-2) F.Huang acknowledges the support from China Postdoctoral Science Foundation(2021M703279) the Science and Technology Plan from Liaoning Province(2022-BS-002) the Innovation Foundation from Institute of Metal Research(2022-PY15) 

主　　题：catalysis catalyst dispersed 

摘      要：CONSPECTUS:Supported metal catalyst,has been one of the most important systems in the field of heterogeneous *** great complexity of both the compositions and structures of such supported metal catalysts provides a great degree of freedom for tuning their catalytic properties,which has essentially triggered the explosive growth in research on design and control active metals’surface structures for *** ideal metal catalyst theoretically features maximum active sites and optimal intrinsic reactivity to facilitate a desired chemical *** by the catalytic concepts brought by natural enzymes and homogeneous catalysis,the fabrication of heterogeneous catalysts with atomically dispersed metal atoms has attracted much attention and been extensively explored in recent *** dispersed metal catalysts(ADMCs)including single-atom catalyst(SACs)and fully exposed cluster catalyst(FECCs),as shining stars in heterogeneous catalysts have recently drawn much *** advantages of ADMCs mainly include the following three aspects:(1)the fully exposed active metal atoms can realize the utmost atomic utilization efficiency and reduce the cost of catalysts;(2)the geometric and electronic structure can be effectively regulated by altering the coordination environments of metal atoms and then further tuning the catalytic performance in terms of activity,selectivity,and stability;(3)the precisely designed structures provide a promising platform for digging the structure−performance relationships of active sites with the assistance of theoretical *** to these advantages,ADMCs have been used in thermal-catalysis,electrocatalysis,photocatalysis,*** *** this Account,a summary of recent progress regarding ADMCs for heterogeneous thermal catalysis in our group will be presented from the following ***,an overview of great opportunities brought by nanodiamond and its derivatives as substrates for anchoring atomically di