Fabrication of N,S co-doped carbon immobilized high-density Co single atoms toward electro-oxidation of organic sulfides with water as feedstock
作者机构：Tianjin Key Laboratory of Organic Solar Cells and Photochemical ConversionTianjin Key Laboratory of Advanced Functional Porous MaterialsInstitute for New Energy Materials&Low-Carbon TechnologiesTianjin University of TechnologyTianjin 300384China Shanghai Synchrotron Radiation FacilityShanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Department of ChemistryThe Chinese University of Hong KongShatinNew TerritoriesHong Kong 999077China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2023年第16卷第5期
页 面：6593-6600页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：the National Natural Science Foundation of China(Nos.22275139,21773288,and U1932119) the National Key Basic Research Program of China(No.2017YFA040340) the Natural Science Foundation of Tianjin City of China(No.18JCJQJC47700)
主 题：single-atom cobalt high density selective oxidation electrocatalysis
摘 要：Development of high-density single atoms site(SAs)electrocatalysts is highly desirable due to their extraordinary catalytic ***,their synthesis is still challenging and their anticorrosion capacities in electrolyte(particularly in acidic electrolyte)are ***,we have constructed N,S co-doped carbon to anchor~10 wt.%Co SAs(Co-SAs/NSC)via a novel polymerization–sulfurization–pyrolysis strategy toward selective electro-oxidation of thioethers in acidic *** asobtained Co SAs has a coordination geometry of Co-S_(2)N_(4),exhibiting excellent electrocatalytic activity and robust *** a low potential of 1.40 V *** hydrogen electrode(RHE),the conversion rate of thioethers over Co-SAs/NSC reaches 99.7%with 100%selectivity and 100%Faraday efficiency(FE)for producing sulfoxide,which is higher than the commercial Pt electrode and the reported state-of-the-art *** calculations and experiments reveal that the Co-S_(2)N_(4)structure endows the outstanding electro-oxidation activity of Co SAs through significantly promoting desorption of the *** work presents a convenient strategy to build high-performance SAs catalysts for the resourceful use of sulfur-containing pollutants.
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