Outstanding high-temperature oxidation-and wear-resistance of WC based cermets
作者机构:Faculty of Materials and Manufacturing Key Laboratory of Advanced Functional Materials Ministry of Education of China Beijing University of Technology Beijing 100124 China Department of Chemical & Materials Engineering University of Alberta Edmonton Alberta T6G 2H5 Canada Xiamen Tungsten Co. Ltd. Xiamen 361009 China
出 版 物:《Journal of Materials Science & Technology》 (材料科学技术(英文版))
年 卷 期:2023年第155卷第24期
页 面:33-46页
核心收录:
学科分类:080503[工学-材料加工工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
基 金:supported by the Beijing Natural Science Foundation(No.2222046) the National Natural Science Foundation of China(Nos.92163107,52101003,52171061,and U20A20236) the National Key R&D Program of China(Nos.2021YFB3501502 and 2021YFB3501504),Haihe Laboratory in Tianjin(No.22HHXCJC00007) the International Research Cooperation Seed Fund of Beijing University of Technology(No.20211222).
主 题:Cermet Anti-oxidation performance Wear mechanism Zirconia
摘 要:The interaction between oxidation and frictional load can greatly deteriorate the performance of ceramic-metal composites.In this work,we used WC-Co cermet as a representative of ceramic-metal composites to study its wear failure behavior and protection effectiveness.It is found that a transition of wear mechanism from mechanical wear to oxidative wear occurs with increasing temperature.The addition of zirconia can significantly improve the anti-oxidation performance and load-bearing capacity of the cermet under the frictional load.This is mainly attributed to the modulation of the tribo-oxide layer constitutions and changes in surface morphology.The zirconia component facilitates the formation of a dense protective oxide layer and reduces the content of brittle oxides on the worn surface.Based on the understanding of the temperature-and oxidation-induced compositional and microstructural evolutions at the sliding contact surface and subsurface,a promising approach is proposed for developing ceramic-metal composites with high wear resistance and anti-oxidation capability.