Highly reinforce the interface stability using 2-Phenyl-1H-imidazole-1-sulfonate electrolyte additive to enhance the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite batteries

作     者：Xin He Yiting Li Wenlian Wang Xueyi Zeng Huilin Hu Haijia Li Weizhen Fan Chaojun Fan Jian Cai Zhen Ma Junmin Nan Xin He;Yiting Li;Wenlian Wang;Xueyi Zeng;Huilin Hu;Haijia Li;Weizhen Fan;Chaojun Fan;Jian Cai;Zhen Ma;Junmin Nan

作者机构：School of ChemistrySouth China Normal UniversityGuangzhou 510006GuangdongChina Guangzhou Tinci Materials Technology Co.Ltd.Guangzhou 510760GuangdongChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第80卷第5期

页      面：10-22,I0001页

核心收录：

学科分类：081702[工学-化学工艺] 0808[工学-电气工程] 08[工学] 0817[工学-化学工程与技术] 

基　　金：financially supported by the Scientific and Technological Plan Projects of Guangzhou City(202103040001) 

主　　题：LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite battery High temperature performance H_(2)O/HF scavenger 2-Phenyl-1H-imidazole-1-sulfonate Electrolyte additive 

摘      要：This work develops 2-Phenyl-1H-imidazole-1-sulfonate(PHIS)as a multi-functional electrolyte additive for H2O/HF scavenging and film formation to improve the high temperature performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/graphite *** 450 cycles at room temperature(25℃),the discharge capacity retentions of batteries with blank and PHIS-containing electrolyte are 56.03%and 94.92%*** 230 cycles at high temperatures(45℃),their values are 75.30%and 88.38%*** enhanced electrochemical performance of the batteries with PHIS-containing electrolyte is supported by the spectroscopic characterization and theoretical *** is demonstrated that this PHIS electrolyte additive can facilitate the construction of the electrode interface films,remove the H2O/HF in the electrolyte,and improve the electrochemical performance of the *** work not only develops a sulfonate-based electrolyte but also can stimulate new ideas of functional additives to improve the battery performance.