Photocatalyst-free visible-light-mediated three-component reaction ofα-diazoesters, cyclic ethers and NaSCN to access organic thiocyanates
Photocatalyst-free visible-light-mediated three-component reaction ofα-diazoesters, cyclic ethers and NaSCN to access organic thiocyanates作者机构:School of Chemistry and Chemical EngineeringQufu Normal UniversityQufu 273165China Qinghai Provincial Key Laboratory of Tibetan Medicine Research and CAS Key Laboratory of Tibetan Medicine ResearchNorthwest Institute of Plateau BiologyXining 810008China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2023年第34卷第2期
页 面:198-201页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:supported by the program of Science and Technology International Cooperation Project of Qinghai Province (No. 2022-HZ-813) the Youth Innovation and Technology Project of High School in Shandong Province (No. 2019KJC021) the Natural Science Foundation of Shandong Province (No. ZR2021MB065) the National Natural Science Foundation of China (No. 31900298)
主 题:Photocatalyst-free Visible-light Three-component reaction Organic thiocyanates
摘 要:A facile and environmentally friendly visible-light-induced three-component reaction of α-diazoesters,cyclic ethers and Na SCN to construct organic thiocyanates has been developed at room temperature. This reaction could occur under photocatalyst-and additive-free conditions to afford a number of organic thiocyanates with moderate to good yield and favorable functional group tolerance.