A thin Si nanowire network anode for high volumetric capacity and long-life lithium-ion batteries

作     者：Ibrahim Saana Amiinu Sumair Imtiaz Hugh Geaney Tadhg Kennedy Nilotpal Kapuria Shalini Singh Kevin M Ryan Ibrahim Saana Amiinu;Sumair Imtiaz;Hugh Geaney;Tadhg Kennedy;Nilotpal Kapuria;Shalini Singh;Kevin M Ryan

作者机构：Bernal InstituteUniversity of LimerickLimerick V94 T9PXIreland Department of Chemical SciencesUniversity of LimerickLimerick V94 T9PXIreland 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第81卷第6期

页      面：20-27,I0002页

核心收录：

学科分类：0808[工学-电气工程] 07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：funded by the Science Foundation Ireland (SFI)under the Principal Investigator Program under contract No.11PI-1148,16/IA/4629 and SFI 16/M-ERA/3419 funding under the European Union’s Horizon 2020 Research and Innovation Program grant agreement No.814464 (Si-DRIVE project) IRCLA/2017/285 and SFI Research Centres AMBER,Ma REI and CONFIRM 12/RC/2302_P2,12/RC/2278_P2,and 16/RC/3918 SFI for SIRG grant No.18/SIRG/5484 support from the Sustainable Energy Authority of Ireland through the Research Development and Demonstration Funding Program (Grant No.19/RDD/548) Enterprise Ireland through the Innovation Partnership Program (Grant No.IP 20190910) support from the SFI Research Centre Ma REI (award reference No.12/RC/2302_P2) support from the SFI Industry RD&I Fellowship Program (21/IRDIF/9876) the EU Horizon 2020 research and innovation program under the Marie Sklodowska-Curie Individual Fellowship Grant (843621) 

主　　题：Si NW anode Silicidation LMO cathode Amorphous ligaments Volumetric capacity Lithium-ion batteries 

摘      要：Silicon nanowires(Si NWs)have been widely researched as the best alternative to graphite anodes for the next-generation of high-performance lithium-ion batteries(LIBs)owing to their high capacity and low discharge ***,growing binder-free Si NW anodes with adequate mass loading and stable capacity is severely limited by the low surface area of planar current collectors(CCs),and is particularly challenging to achieve on standard pure-Cu substrates due to the ubiquitous formation of Li+inactive silicide ***,the growth of densely-interwoven In-seeded Si NWs is facilitated by a thin-film of copper-silicide(CS)network in situ grown on a Cu-foil,allowing for a thin active NW layer(99.6%and stable performance for900 cycles with≈88.7%capacity *** significantly,it delivers a volumetric capacity of≈1086.1 m A h/cm^(3)at *** full-cell versus lithium manganese oxide(LMO)cathode delivers a capacity of≈1177.1 m A h/g at 1C with a stable rate *** electrode architecture represents significant advances toward the development of binder-free Si NW electrodes for LIB application.