Electrochemical borylation of nitroarenes

作     者：Linlin Du Binfeng Zhang Shuohan Ji Hu Cai Hua Zhang 

作者机构：Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials ScienceSchool of Chemistry and Materials ScienceSouth-Central Minzu UniversityWuhan430074China School of Chemistry and Chemical EngineeringNanchang UniversityNanchang330031China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2023年第66卷第2期

页      面：534-539页

核心收录：

学科分类：07[理学] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(21602096)。 

主　　题：electrochemistry borylation nitroarenes arylboronic esters organic synthesis 

摘      要：A simple electrochemically mediated method for the conversion of nitroarenes to aryl boronic esters is presented.Electrochemical borylation of a diverse range of nitroarenes,including the late-stage borylation of bioactive molecules,is furnished at room temperature under simple conditions,thereby demonstrating the broad utility and functional-group tolerance of this protocol.This transformation provides a convenient and practical access to aryl boronic esters from widely available nitroarenes,which would significantly streamline the synthetic process of diverse functionalized arenes.