Recent progress in electrochemical C–N coupling reactions

作     者：Yuan Zhong Hailong Xiong Jingxiang Low Ran Long Yujie Xiong Yuan Zhong;Hailong Xiong;Jingxiang Low;Ran Long;Yujie Xiong

作者机构：Hefei National Research Center for Physical Sciences at the MicroscaleSchool of Chemistry and Materials ScienceNational Synchrotron Radiation LaboratoryUniversity of Science and Technology of ChinaHefeiAnhui 230026China Institute of EnergyHefei Comprehensive National Science Center350 ShushanhuRd.HefeiAnhui 230031China 

出 版 物：《eScience》 (电化学与能源科学（英文）)

年 卷 期：2023年第3卷第1期

页      面：26-37页

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程（可授工学、理学学位）] 070303[理学-有机化学] 0703[理学-化学] 0702[理学-物理学] 

基　　金：This work was financially supported in part by the National Key R&D Program of China(2020YFA0406103) NSFC(21725102,22122506,91961106,U1832156,22105192,22075267) Strategic Priority Research Program of the CAS(XDPB14) the Open Funding Project of National Key Laboratory of Human Factors Engineering(SYFD062010K) Anhui Provincial Natural Science Foundation(2008085J05) Youth Innovation Promotion Association of CAS(2019444) China Post-doctoral Science Foundation(2021M693065,2021TQ0322) 

主　　题：Electrochemical C-N coupling reactions Carbon dioxide Inorganic nitrogenous species Nitrogenous compounds Reactor designs 

摘      要：Electrochemical C–N coupling has generated intense research interest as a promising approach to reduce carbon and nitrogen emissions and store excess renewable electricity in valuable chemicals(e.g.,urea,amides,and amines).In this review,we discuss the emerging trends in electrocatalytic C–N coupling reactions using CO_(2) and inorganic nitrogenous species(i.e.,dinitrogen(N_(2))),nitrate(NO_(2)^(-)),nitrite(NO_(3)^(-)),and ammonia(NH_(3))as raw *** related reaction mechanisms and potential design principles for advanced electrocatalysts are *** addition,the effects of different reactors,including H-cells,membrane-based flow reactors,and membrane electrode assembly electrolyzers,on the coupling reactions are ***,the current challenges and future opportunities in this field are *** aim to provide an up-to-date overview of the electrochemical C–N coupling system to advance progress toward its practical application.