Controlled synthesis of GeSe_(2) and GeSe nanostructures induced by TBAB

作     者：Huan Yang Yue Wu Li-Yan Hu Juan-Juan Wang Fang Wang Xiao-Hong Xu Huan Yang;Yue Wu;Li-Yan Hu;Juan-Juan Wang;Fang Wang;Xiao-Hong Xu

作者机构：School of Chemistry and Materials Science of Shanxi Normal University and Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of EducationTaiyuan031000China Research Institute of Materials Science of Shanxi Normal University and Collaborative Innovation Center for Advanced Permanent Magnetic Materials and Technology of Ministry of EducationTaiyuan031000China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2023年第42卷第1期

页      面：189-197页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：supported by the National Natural Science Foundation of China(Nos.51971122 and 12174237) Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2021Y440)。 

主　　题：GeSe_(2) GeSe Borane tert-butylamine complex(TBAB) Liquid-phase method Bandgaps 

摘      要：Ge-based selenides have attracted extensive attention as promising candidates for future optoelectronic applications.Despite great progress has been achieved,the controlled synthesis of GeSe2and GeSe nanostructures and understanding the relative growth mechanisms of them are still lacking.Herein,monodispersed GeSe_(2) nanoflowers with a diameter of~4μm and highly uniform GeSe nanoparticles with a lateral size of~100 nm are presented by using a colloidal synthetic method.It is found that borane tert-butylamine complex(TBAB)plays an important role in determining the Ge-Se crystal phases due to its moderately reducibility.Furthermore,the coexistence of GeSe_(2) and GeSe phases can also be acquired by precisely controlling the amount of TBAB.In brief,this work provides both new insights of the phase control of Gebased selenides by liquid-phase method and a practical means of producing well-controlled germanium selenide nanostructures.