Noble-metal free plasmonic nanomaterials for enhanced photocatalytic applications—A review
作者机构：International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an710049China School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an710049China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2022年第15卷第12期
页 面：10268-10291页
核心收录：
学科分类：07[理学] 070304[理学-物理化学(含∶化学物理)] 070205[理学-凝聚态物理] 0817[工学-化学工程与技术] 0806[工学-冶金工程] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学]
基 金：the financial support from the National Natural Science Foundation of China(No.52025061) Royal Society-Newton Advanced Fellowship grant(No.NAF/R1/191163) supported by the China Fundamental Research Funds for the Central Universities.
主 题：localized surface plasmon resonance(LSPR) noble-metal free plasmonic nanomaterials photocatalysis
摘 要：Plasmonic nanomaterial catalysis is currently at the frontier of photocatalysis,overcoming the limitations of wide bandgap semiconductors for light absorption.Its localized surface plasmon resonance(LSPR)properties allow broad ultraviolet-visible-near infrared ray(UV-vis-NIR)absorption,making it an ideal material for solar energy conversion.Most plasmonic nanostructures rely on precious metals.Although noble metal plasmonic nanomaterials have proven to be one of the strategies for enhancing photocatalytic activity,their expensive cost and limitations in light absorption range have hindered their practical application.As a result,noble-metal free plasmonic nanomaterials have risen to the top of the research priority list.Therefore,this paper reviews the fundamental principles and classification of the LSPR effect of noble-metal free plasmonic nanomaterials in photocatalytic and their recent applications in hydrogen generation,carbon dioxide reduction,and pollutant degradation.Specific cases elucidate the possible working mechanism of enhanced photocatalysis by noble-metal free plasmonic nanomaterials.Finally,the challenges and future opportunities for noble-metal free plasmonic nanomaterials in energy conversion and storage are discussed and envisioned.
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