Electrochemical Oxidative [4+2] Annulation of Different Styrenes toward the Synthesis of 1,2-Dihydronaphthalenes
[4+2] Annulation of Different Styrenes toward the Synthesis of 1,2-Dihydronaphthalenes作者机构：College of Chemistry and Molecular SciencesInstitute for Advanced Studies(IAS)Wuhan UniversityWuhanHubei 430072 National Research Center for Carbohydrate SynthesisJiangxi Normal UniversityNanchangJiangxi 330022
出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)
年 卷 期：2022年第4卷第5期
页 面：1557-1564页
学科分类：07[理学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学]
基 金：supported by the National Natural Science Foundation of China(22031008) Science Foundation of Wuhan(2020010601012192) The Program of Introducing Talents of Discipline to Universities of China(111 Program)is also appreciated.
主 题：electrochemical synthesis styrenes [4+2]annulation 1,2-dihydronaphthalenes regioselectivity and diastereoselectivity
摘 要：A[4+2]annulation of two different styrenes to construct polysubstituted 1,2-dihydronaphthalenes was achieved.This transformation proceeded smoothly under electrochemical oxidative conditions without metal catalysts and external oxidants.A series of polysubstituted 1,2-dihydronaphthalenes were obtained with high regioselectivity and diastereoselectivity.Moreover,polysubstituted 1,2-dihydronaphthalenes were further transformed to polysubstituted 1,2,3,4-tetrahydronaphthalenes and polysubstituted naphthalenes,which show great potential in synthetic applications.
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