A new insight into the unique magneto-optical effect of layered perovskite(C_(6)H_(5)C_(2)H_(3)FNH_(3))_(2)MnCl_(4)
作者机构:State Key Laboratory of Coordination ChemistrySchool of Chemistry and Chemical EngineeringNanjing UniversityNanjingPR China Chaotic Matter Science Research CenterFaculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhouPR China Jiangxi Provincial Key Laboratory of Functional Molecular Materials ChemistryJiangxi University of Science and TechnologyGanzhouPR China Wuhan National High Magnetic Field Center and School of PhysicsHuazhong University of Science and TechnologyWuhanPR China Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy ApplicationSchool of Physical Science and TechnologySuzhou University of Science and TechnologySuzhouPR China State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal ResourcesSchool of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilinPR China
出 版 物:《聚集体(英文)》 (Aggregate)
年 卷 期:2023年第4卷第3期
页 面:120-125页
核心收录:
学科分类:0710[理学-生物学] 07[理学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0701[理学-数学] 0702[理学-物理学] 070101[理学-基础数学]
基 金:National Key Research and Development Program of China,Grant/Award Numbers:2018YFA0306004,2017YFA0204800 National Natural Science Foundation of China,Grant/Award Numbers:21973038,21805119,12064002,21875093,22105089,61904119,11974126 The Joint Fund for Regional Innovation and Development,Grant/Award Number:U20A2073 Natural Science Foundation of Jiangxi Province,Grant/Award Numbers:20204BCJ22015,20202ACBL203001 Natural Science Foundation of the Jiangsu Higher Education Institutions of China(,Grant/Award Number:20KJB140019) Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry,Grant/Award Number:20212BCD42018 Interdisciplinary program of Wuhan National High Magnetic Field Center,Grant/Award Number:WHMFC202133
主 题:magnetic order magneto-optical effect optical hysteresis optical phenomena
摘 要:Magnet-optical materials embracing coupled magnetic and photoluminescent properties in single phase are promising in microelectronics and optoelectronic ***,the current research mainly focuses on traditional inorganic materials,and there are few reports on molecule ***,we synthesized an organic–inorganic hybrid complex((C_(6)H_(5)C_(2)H_(3)FNH_(3))_(2)MnCl_(4)(1)with perovskite *** measurements show that 1 not only behaves as an antiferromagnet with spin canting but also exhibits unusual fluorescent ***,under the magnetic field at different temperatures,the luminous intensity of 1 changed,and a red-shift occurred with obviously optical *** phenomena directly prove the existence of magneto-optical coupling in *** interestingly,the optical hysteresis can be observed in both low and high field,which is unprecedented in other molecular *** in traditional inorganic materials,it can only be observed in strong *** special function provides the possibility for the application of low energy consumption optoelectronic devices.